Poliolefinas reforzadas con óxido de grafeno reducido. Mediciones viscoelásticas
DOI:
https://doi.org/10.29105/ingenierias25.92-52Palabras clave:
Grafeno, Composites, Viscoelasticidad, Polietileno de Alta Densidad, PolipropilenoResumen
Se analiza el efecto de óxido de grafeno reducido y del óxido de polietileno sobre las propiedades viscoelásticas de HDPE y PP. Los gráficos de la viscosidad dinámica presentan curvas muy similares en todos los casos. Utilizando porcentajes de rGO de 0.1% con 2% de PEO, se obtienen valores del módulo elástico cuatro veces más grandes que los de HDPE puro y tres veces más que el del PP puro. Con 0.5% de rGO en ambos composites, manteniendo el mismo porcentaje de PEO, se obtiene un módulo elástico tres veces más grande que el de las poliolefinas puras.
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Cornelia Vasile, Handbook of Polyolefins. 2nd Ed., Revised and Expanded, Marcel Dekker, New York, USA (2000). DOI: https://doi.org/10.1201/9780203908716
Andrew J. Peacock, Handbook of Polyethylene. Structures, Properties and Applications, Marcel Dekker, New York, USA (2000). DOI: https://doi.org/10.1201/9781482295467
Clive Maier, Teresa Calafut, Polypropylene. The Definitive User’s Guide and Databook, Plastic Design Library, New York, USA (1998).
Ehsan Bafekrpour (Ed.), Advanced Composite Materials: Properties and Applications, De Gruyter Open Ltd, Berlin, Germany (2017). DOI: https://doi.org/10.1515/9783110574432
Deborah D. L. Chung, Composite Materials. Science and Applications. 2nd Ed., Springer Verlag, London (2010).
Klaus Friedrich, Stoyko Fakirov, Zhong Zhang, Polymer Composites. From Nano to Macro Scale, Springer, New York, USA (2005). DOI: https://doi.org/10.1007/b137162
I. Krupa, I. Novák, I. Chodák, Electrically and thermally conductive polyethylene/graphite composites and their mechanical properties, Synthetic Metals 145 (2004) 245–252. DOI: https://doi.org/10.1016/j.synthmet.2004.05.007
A Marcincin et al, Spinning, structure and properties of PP/CNTs and PP/carbon black composite fibers, 2014 IOP Conf. Ser.: Mater. Sci. Eng. 64 012004. DOI: https://doi.org/10.1088/1757-899X/64/1/012004
Zdenko Spitalsky, Dimitrios Tasisb, Konstantinos Papagelis, Costas Galiotis, Carbon nanotube polymer composites: Chemistry, processing, mechanical and electrical properties, Progress in Polymer Science 35 (2010) 357–401. DOI: https://doi.org/10.1016/j.progpolymsci.2009.09.003
Maziyar Sabet, Hassan Soleimani, Mechanical and electrical properties of low density polyethylene filled with carbon nanotubes 2014 IOP Conf. Ser.: Mater. Sci. Eng. 64 012001. DOI: https://doi.org/10.1088/1757-899X/64/1/012001
Saibom Park, Siyao He, Jianeng Wang, Andreas Stein, Christopher W. Macosko, Graphene-polyethylene nanocomposites: Effect of graphene functionalization, Polymer 104 (2016) 1-9. DOI: https://doi.org/10.1016/j.polymer.2016.09.058
Huanmin Li, Xu-Ming Xie, Polyolefin-functionalized graphene oxide and its GO/HDPE nano-composite with excellent mechanical properties, Chinese Chemical Letters 29 (2018) 161–165.
Bin Wang, Dan Peng, Ruihua Lv, Bing Na, Hesheng Liu, Zhong Yu, Generic melt compounding strategy using reactive graphene towards high performance polyethylene/graphene nanocomposites, Composites Science and Technology 177 (2019) 1–9 DOI: https://doi.org/10.1016/j.compscitech.2019.04.013
Muhammad Z. Iqbal, Ahmed A. Abdala, Vikas Mittal, Sӧnke Seifert, Andrew M. Herring, Matthew W. Liberatore, Processable conductive graphene/polyethylene nanocomposites: Effects of graphene dispersion and polyethylene blending with oxidized polyethylene on rheology and microstructure, Polymer 98 (2016) 143-155. DOI: https://doi.org/10.1016/j.polymer.2016.06.021
Hongyu Chen, Valeriy V. Ginzburg, Jian Yang, Yunfeng Yang, Wei Liu,Yan Huang, Libo Du, Bin Chen, Thermal conductivity of polymer-based composites: Fundamentals and applications, Progress in Polymer Science 59 (2016) 41–85. DOI: https://doi.org/10.1016/j.progpolymsci.2016.03.001
A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, A. K. Geim, The electronic properties of graphene, Rev. Mod. Phys (2009) Vol. 81, No. 1 pp 109-162 DOI: https://doi.org/10.1103/RevModPhys.81.109
Carlos A. Guerrero Salazar, Paloma B. Jiménez Vara, Virgilio A. González González, Tania E. Guerrero Salas, Composites de polietilen tereftalato (PET) con óxido de grafeno reducido (rGO), a ser publicado en Ingenierías (2019).
Mayra I. Llamas Hernández, Carlos A. Guerrero Salazar, Martín E. Reyes Melo, Juan F. Luna Martínez, Comportamiento elástico y morfológico de compuestos polipropileno-grafeno, Ingenierías (2015) Vol XVIII, 68, pp 32-40
Daniela C. Marcano, Dmitry V. Kosynkin, Jacob M. Berlin, Alexander Sinitskii, Zhengzong Sun, Alexander Slesarev, Lawrence B. Alemany, Wei Lu, James M. Tour, Improved Synthesis of Graphene Oxide, ACS Nano, Vol. 4, No. 8, 4806-4814, 2010. DOI: https://doi.org/10.1021/nn1006368
Hua Bai, Chun Li, Gaoquan Shi, Functional Composite Materials Based on Chemically Converted Graphene, Adv. Mater. 2011, 23, 1089–1115. DOI: https://doi.org/10.1002/adma.201003753
Jianfeng Shen, Yizhe Hu, Min Shi, Xin Lu, Chen Qin, Chen Li, Mingxin Ye, Fast and Facile Preparation of Graphene Oxide and Reduced Graphene Oxide Nanoplatelets, Chem. Mater. 2009, 21, 3514–3520. DOI: https://doi.org/10.1021/cm901247t
L. Stobinski, B. Lesiak, A. Malolepszy, M. Mazurkiewicz, B. Mierzwa, J. Zemek, P. Jiricek, I. Bieloshapka, Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods, Journal of Electron Spectroscopy and Related Phenomena 195 (2014) 145–154. DOI: https://doi.org/10.1016/j.elspec.2014.07.003
D.P. Hansora, N.G. Shimpi, S. Mishra, Graphite to Graphene via Graphene Oxide: An Overview on Synthesis, Properties, and Applications, JOM, Vol. 67, No. 12, 2015, pp 2855-2868. DOI: https://doi.org/10.1007/s11837-015-1522-5
Huanmin Li, Xu-Ming Xie, Polyolefin-functionalized graphene oxide and its GO/HDPE nanocomposite with excellent mechanical properties, Chinese Chemical Letters 29 (2018) 161–165. DOI: https://doi.org/10.1016/j.cclet.2017.06.001
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Derechos de autor 2022 Carlos A. Guerrero Salazar, Mayra Llamas Hernández, Antonio Elizondo Martínez, M. Edgar Reyes Melo, Tania E. Guerrero Salas
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
