Síntesis y caracterización del Mg(BOB)2 como electrolito para baterías recargables de iones de magnesio
DOI:
https://doi.org/10.29105/ingenierias26.95-796Palabras clave:
Mg(BOB)2, electrolito, deposición/disolución de MgResumen
Se llevó a cabo el proceso de obtención libre de solventes de la sal bis(oxalato)borato de magnesio (Mg(B(C2O4)2)2, Mg(BOB)2), la cual es potencialmente viable para ser utilizada como material electrolítico en baterías recargables de iones de magnesio (RMIB). La síntesis utilizada fue por estado sólido donde en un primer paso se mezcló manual y homogéneamente, dentro de un mortero de ágata, sus tres precursores; ácido oxálico, ácido bórico e hidróxido de magnesio con una relación molar de 4:2:1, respectivamente. Como segundo paso, y debido a que se utilizan compuestos higroscópicos, se evitó la exposición de manera prolongada a la humedad ambiental llevándolos a un secado dentro un horno de vacío a 60 °C durante 1 h continua seguido de un tratamiento térmico de 110 °C por 3 h, para la eliminación del agua residual previo a la temperatura de síntesis de 150 °C. El Mg(BOB)2 sintetizado se caracterizó por difracción de rayos X (DRX) y por microscopía electrónica de barrido (MEB). Los resultados obtenidos mediante espectroscopia infrarroja por transformada de Fourier (FTIR) dentro del rango de número de onda de 4000–400 cm−1 confirmaron la aparición de los grupos funcionales del Mg(BOB)2, identificados por sus bandas características de absorción C=O, C-O-B-O-C, O-B-O y B-O. Además, el polvo del Mg(BOB)2 se utilizó para preparar un electrolito líquido con el solvente tetrahidrofurano (THF) y se evaluó en celdas de tres electrodos así como en medias celdas prototipo, caracterizadas con curvas de voltamperometría cíclica (VC).
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Derechos de autor 2023 Jesús Guzmán Torres, Edgar González Juárez, Salome Maribel De la Parra Arciniega, Arián Espinosa Roa, Eduardo Maximiliano Sánchez Cervantes
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
